Hi Nikki,
It all comes down to what the HMRC says about business expenses, that they MUST be "wholly and exclusively" for the business. Using the new car to run the family around is obviously a personal expense and it was bought for that purpose.
As Steve says, if he does use the car for some business mileage then he will need to keep records of his business mileage and claim back 45p per mile for the first 10,000 business miles then 25p per mile for any business miles above that.
He MAY be able to apportion some of the cost of the car (the business portion only), but definitely not the whole cost. But if he does this I'm not sure he can then claim mileage because that is usually for personal cars used for business.
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