Not sure if there is a fool proof way of remembering it really, other then knowing the double entry that is necessary, and which element of the double entry has the vat. Example:
Sales of £100 +vat@20% = £120
so for a cash sale you MUST get £120 therefore £120 MUST go into cash. So if one side (debit in this case) MUST be gross then the other side (credit in this case) will have the net and vat parts, so credit sales £100 and credit VAT £20
same goes for sales on credit, your debtor MUST owe the gross amount, therefore the sales (again obviously credit side) has the net and vat.
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