Hi Debra
I don't know of anywhere on this site that has the information you asked about, however, I can add a little more to Lainy's comments that may also help.
If you type the words P46 form into Google, you can still get one of the old P46 style forms to download that helps you to get the information you need regarding the employees.
As well as everything Lainy has already told you, it's important to find out whether each employee has another job, pension, first job of the year etc, as this information allows you to give them the right tax code if the employee doesn't have a recent P45 form.
You will also need the full details, name, trading address, NI Number, Business Name, how many employees they will be employing etc, UTR number if Limited etc of who the 'employer' is going to be, as they will probably want you to register them as an Employer with HMRC - you can do this online at the same time as registering yourself as their agent.
Have fun, it's easy once you've done one - unless there's any unusual circumstances!
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